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物理化学教学大纲(Syllabus of Physical Chemistry)Syllabus of Physical ChemistryCourse Name: Physical ChemistryEnglish Name: Physical ChemistryCourse number: 01000211Course category: specialized coursesCourse requirements: required coursesCurriculum attributes: independent teachingThe total class hours: 102 hours, total credits 6Experimental class hours: 34 hours (separate classes)Semester: fourth, fifth semesterApplicable Specialty: Chemical Engineering, Applied ChemistryPrerequisite courses: Advanced Mathematics (differential, integral), physics, inorganic chemistry, organic chemistryFirst, the nature and task of curriculumPhysical chemistry focuses on chemical change and phase change law of balance and the rate of change of law, is a required basic course of chemical engineering and technology, applied chemistry, biological engineering, food, materials, pharmaceutical, biotechnology and other professional, it includes theory teaching and experiment teaching. Experimental teaching starts separately. Through the study of this course, students should firmly grasp the basic concepts and calculation methods of physical chemistry, and should also be trained in general scientific methods and the cultivation of logical thinking ability. This kind of training and training should be run through the entire process of classroom teaching, so that students understand and grasp how the results of induction and deduction, or by the assumptions and models up to the theory, method and combining the concrete conditions of solving practical problems by using the theory of.Two, the content and basic requirements of the courseThe theoretical research methods of physical chemistry include thermodynamic method, statistical mechanics method and quantum mechanics method. From the research content including macro, micro and sub micro, engineering students, thermodynamics method and the macro content is basic and important, the importance of two methods and content is increasing. For engineering majors, quantum mechanics methods generally do not require or otherwise set up courses.Here are the basic requirements and contents listed in each chapter. The basic requirements are divided into three levels: understanding, understanding and mastery. The theory of teaching hours less than 85 hours of professional, a number marked content, does not belong to the basic requirements.Chapter 1. PVT properties of matterFirst, the basic requirements of this chapterMaster the equation of state of ideal gas.Grasp the macroscopic definition and microscopic model of ideal gasMaster the concept and calculation of partial pressure and volume.Understanding the deviation and criticality of real gas and ideal gas.Grasp the concept of saturated vapor pressure.Understanding the Fan Dehua equation of state, the corresponding state principle and the compressibility factor diagram, we can understand the contrast equation of state and other real gas equations.Two, teaching content1. ideal gas and equation of state, law of partial pressure, law of partial volume.2. real gasThe deviation between real gas and ideal gas, Fan Dehua equation, the liquefaction of real gas (C02 diagram of p-V), critical phenomena and critical parameters.3. the corresponding state principle and diagram of compressibility factorBy comparing the parameters and the corresponding state principle, the generalized computation of the compressibility factor diagram is carried out.The second chapter is the first law of thermodynamicsFirst, the basic requirements of this chapterUnderstanding the basic concepts of system and environment, state, process, state function and path function, and understanding the concept of reversible process.Grasp the first law of thermodynamics, literal expression and mathematical expression.Understanding the concepts of work, heat, thermodynamic energy, enthalpy, heat capacity, molar enthalpy of phase change, standard molar enthalpy of reaction, standard molar enthalpy of formation, standard molar enthalpy of combustion, etc.Grasp the first law of thermodynamics in the pure P V T change, phase change and chemical changes in the application, master the calculation of various processes of work, heat, thermodynamics, energy change, enthalpy change method.Two, teaching content1. Basic concepts and terminologySystem, environment, nature, state, state function, equilibrium state, process and approach.2. The first law of thermodynamicsWork, heat, thermodynamic energy, the first law of thermodynamics. Constant volume heat and constant pressure heat and enthalpy.3. Calculation of volume work in reversible processReversible process, constant temperature reversible process and calculation of adiabatic reversible process work.4. Heat capacityMean heat capacity and true heat capacity.Molar heat capacit
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