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龚流柱 中国科学技术大学合肥微尺度物质科学国家实验室,化学系,Gold Catalysis,金属有机化学-均相催化,2010-11-23,General Introduction of Gold,Atomic Number: 79 Atomic Weight: 196.966569 Common Oxidation State: +3, +1,Electron Shell Configuration:,1s2, 2s2 2p6, 3s2 3p6 3d10, 4s2 4p6 4d10 4f14, 5s2 5p6 5d10,5f0 6s1 6p0,Au(I) and Au(III) are able to form complexes with heteroatom and unsaturated Hydrocarbons,-Complexes of Gold in Any of Its Oxidation States,Chalk, A. J. Am. Chem. Soc. 1964, 86, 4733 Strahle, J. and Calderazzo, F. et al, Organometallics 1987, 6, 1207 Mingos, D. M. P. et al, Angew. Chem. Int. Ed. Engl. 1995, 34, 1894.,Nesmeyanov, A. N. et al, J. Organomet. Chem. 1974, 65, 131. Bertrand, G. et al, Proc. Natl. Acad. Sci. U. S. A. 2007, 104, 13569,Activation of Carbonyl Groups,Aldol Reaction,Ito, Y.; Sawamura, M.; Hayashi, T. J. Am. Chem. Soc. 1986, 108, 6405; Tetrahedron Lett. 1987, 28, 6215 and 1988, 29, 239. Hayashi, T. ; Sawamura, M.; Ito, Y. 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